No, most VPNs don't work at all with bet365  if the site detects that you're using a VPN, it will deny you access to your account. So, you need to make sure you purchase a VPN that works with bet365 and also has servers in locations that work with bet365.
There are several reasons why bet365 accounts can be restricted, including matched betting, unreasonable betting behaviour, GamStop (self-exclusion), and exploitation of bonuses.